102095-77-2Relevant academic research and scientific papers
A study on the synthesis of structural analogs of bis-indole alkaloid caulerpin: a step-by-step synthesis of a cyclic indole-tetramer
Talaz, Oktay,Saracoglu, Nurullah
, p. 1902 - 1910 (2010)
The syntheses of structural isomers of bis-indole alkaloid caulerpin are investigated. Construction of the caulerpin skeleton is based on the Fisher indolization reaction of the appropriate cyclooctane-diones or cyclooctanone. In addition, a step-by-step
Study on the Transannular Lead Tetraacetate Oxidation of Some Medium-sized Ring Diketone Bis(arylhydrazones)
Malamidou-Xenikaki, Elizabeth,Alexandrou, Nicholas E.
, p. 280 - 286 (2007/10/02)
Oxidation of bis(arylhydrazones) 1a-d of 1,5-cyclooctanedione with lead tetraacetate mainly leads, via a transannular reaction, to the corresponding bicyclic bis(arylazo) compounds 3a-d, whereas bis(arylhydrazones) 2a-d of 3,8-cyclodecadiene-1,6-dione under the same conditions mainly give monocyclic bis(acetoxy)bis(arylazo) products 6a-d.The reaction of bis(arylazo) derivatives 3 with sulfuric acid is also examined.
