1021168-35-3Relevant articles and documents
Nucleophilic addition of potassium organotrifluoroborates to chiral cyclic N-acyliminium ions: stereoselective synthesis of functionalized N-heterocycles
Vieira, Adriano S.,Ferreira, Fernando P.,Fiorante, Pedro F.,Guadagnin, Rafael C.,Stefani, Hélio A.
, p. 3306 - 3314 (2008/09/21)
The stereoselective nucleophilic addition of potassium aryl- and alkynyltrifluoroborates to cyclic N-acyliminium ion derivatives from N-benzyl-3,4,5-triacetoxy-2-pyrrolidinone, affording the respective 5-substituted 2-pyrrolidinone is described. The products were obtained in moderate to good yields and with preference for the syn diastereomer.