112981-69-8

Basic information

• Product Name: (3 5 BIS(TRIFLUOROMETHYL)PHENYL)MAGNESI&
• Synonyms: (3 5 BIS(TRIFLUOROMETHYL)PHENYL)MAGNESI&;3,5-Bis(trifluoromethyl)phenylmagnesium bromide 0.5M in tetrahydrofuran;3,5-bis(trifluoromethyl)phenylmagnesium bromide solution;3,5-BIS(TRIFLUOROMETHYL)PHENYLMAGNESIUM BROMIDE, 0,5M SOLUTION IN THF;3,5-Bis(trifluoromethyl)phenylmagnesium bromide, 0.5M solution in THF, AcroSeal§3;3,5-Bis(trifluoromethyl)phenylmagnesium bromide solution 0.5 in THF;3,5-Bis(trifluoromethyl)phenylmagnesium bromide, 0.5M solution in THF, AcroSeal;3,5-Bis(trifluoroMethyl)phenylMagnesiuM broMide, 0.5 M solution in THF, J&KSeal
• CAS NO: 112981-69-8
• Molecular Formula: C8H3BrF6Mg
• Molecular Weight: 317.3088392
• Product Categories: Aryl;Grignard Reagents;Organometallic Reagents
• Mol File: 112981-69-8.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 65°C/760mmHg
• Flash Point: −4 °F
• Appearance: /
• Density: 1.015 g/mL at 25 °C(lit.)
• Vapor Pressure: 22.1mmHg at 25°C
• Storage Temp.: Flammables + water-Freezer (-20°C)e area
• CAS DataBase Reference: (3 5 BIS(TRIFLUOROMETHYL)PHENYL)MAGNESI&(CAS DataBase Reference)
• NIST Chemistry Reference: (3 5 BIS(TRIFLUOROMETHYL)PHENYL)MAGNESI&(112981-69-8)
• EPA Substance Registry System: (3 5 BIS(TRIFLUOROMETHYL)PHENYL)MAGNESI&(112981-69-8)

Safety Data

• Hazard Codes: F,Xi,C
• Statements: 11-19-36/37/38-37-34-14-40
• Safety Statements: 16-26-29-33-36-45-36/37/39
• RIDADR: UN 2924 3/PG 2
• WGK Germany: 1
• Hazardous Substances Data: 112981-69-8(Hazardous Substances Data)

Usage

Chemical Properties

Dark brown solution

InChI:InChI=1/C8H3F6.BrH.Mg/c9-7(10,11)5-2-1-3-6(4-5)8(12,13)14;;/h2-4H;1H;/q-1;;+2/p-1

Upstream product

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• 159418-71-0 [di-3,5-bis(trifluoromethyl)phenyl](diethyl-amino)phosphine 

Downstream Products

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• 68120-60-5 1-(3,5-bis(trifluoromethyl)phenyl)ethan-1-ol 
• 67570-38-1 α,α-dimethyl-3,5-bis(trifluoromethyl)benzenemethanol 
• 159418-71-0 [di-3,5-bis(trifluoromethyl)phenyl](diethyl-amino)phosphine 
• 62022-60-0 1-(3,5-Bis-trifluoromethyl-phenyl)-1-cyclopropyl-ethanol 
• 1026320-68-2 2-(3,5-bis-trifluoromethyl-phenyl)-4,4-dimethyl-pentan-2-ol 
• 322640-44-8 (2S,5R)-2-[1-(3,5-Bis-trifluoromethyl-phenyl)-1-methyl-ethyl]-5-methyl-cyclohexanone 
• 845965-28-8 (S)-1,1-bis(3,5-bis(trifluoromethyl)phenyl)tetrahydro-1H,3H-pyrrolo[1,2-c]oxazol-3-one 
• 848821-76-1 (S)-(-)-α,α-bis[3,5-bis(trifluoromethyl)phenyl]-2-pyrrolidinemethanol 
• 299176-62-8 (3,5-bis(trifluoromethyl)phenyl)diphenylphosphine oxide 
• 185543-59-3 2-{bis-[3,5-bis-(trifluoromethyl)phenyl]-phosphino}-2'-hydroxy-3'-phenylbiphenyl 
• 17197-30-7 SnMe₃(C₆H₃(CF₃)2-3,5) 
• 328-76-7 (ph-3.5-(CF₃)2)SiCl₃ 

Relevant articles and documents

Enantioselective synthesis of diaryl aziridines using tetrahydrothiophene- based chiral sulfides as organocatalysts

This work describes catalytic and asymmetric aziridinations (15 examples, 95-98% ee) of benzyl bromide and imines via the imino Corey-Chaykovsky reaction using (thiolan-2-yl)diarylmethanol benzyl ether as an organocatalyst. The catalyst and analogues thereof were prepared through an expeditious and efficient synthetic route featuring a double nucleophilic substitution and Shi epoxidation as key steps.

Quinoline derivatives and organic electroluminescent devices

Quinoline derivatives represented by formula (1) wherein two or more of substituents R1 to R7 are each a group of formula (2). It is preferable that among the substituents R1 to R7, at least one of the substituents other than those of general formula (2) be an electron-whithdrawing group. In general formula (2), Q is a carbo- or hetero-aryl group; at least one of the substituents RQ on the group Q is preferably an electron-donating group; and the number (n) of double bonds is preferably 1 to 3. Use of such derivatives in an organic EL device provided with a layer of an organic compound and two electrodes sandwiching the layer as the organic compound gives devices emitting yellow to red light with high brightness and high efficiency. Further, doping a hole transport layer with such derivatives realizes organic EL devices capable of emitting lights of resultant colors (e. g., white) composed of lights from light-emitting and hole transport layers.

Triarylphosphine oxide derivatives containing fluorine substituents

The invention relates to triarylphosphine oxide derivatives containing fluorine substituents that are useful as a monomer in preparation of polymers with improved properties such as chemical resistance and electrical insulating property as well as adhesiveness and flame retardancy. The triarylphosphine oxide derivatives containing fluorine substituents are represented by the chemical formula1: wherein R1and R2are independently a fluorine-substituted alkyl group; and X is hydrogen, a nitro group, or an amine group.