1021466-01-2Relevant academic research and scientific papers
The Coming of Age in Iodane-Guided ortho-C?H Propargylation: From Insight to Synthetic Potential
Izquierdo, Susana,Bouvet, Sébastien,Wu, Yichen,Molina, Sonia,Shafir, Alexandr
, p. 15517 - 15521 (2018/10/02)
As early as 1991 Ochiai et al. reported that an acid-activated form of phenyliodine diacetate, PhI(OAc)2, undergoes a reaction with propargyl-silanes, germanes and stannanes to give the ortho-propargyl iodobenzene. This formal C?H alkylation wa
Cyclization reactions involving palladium-catalyzed carbene insertion into aryl halides
Kudirka, Romas,Van Vranken, David L.
, p. 3585 - 3588 (2008/09/20)
(Chemical Equation Presented) Palladium is shown to catalyze the insertion of trimethylsilylmethylene into aryl halides, leading to benzylpalladium intermediates that cyclize to give indenylsilanes through carbopalladation of pendant alkenes or allenes. A
