102147-48-8Relevant academic research and scientific papers
DABSO-based, three-component, one-pot sulfone synthesis
Deeming, Alex S.,Russell, Claire J.,Hennessy, Alan J.,Willis, Michael C.
supporting information, p. 150 - 153 (2014/01/23)
The addition of Grignard reagents or organolithium reagents to the SO 2-surrogate DABSO generates a diverse set of metal sulfinates, suitable for direct conversion to sulfone products. The metal sulfinates can be trapped in situ with a wide range of C-electrophiles, including alkyl, allyl, and benzyl halides, epoxides, and (hetero)aryliodoniums.
THE INVENTION OF RADICAL REACTIONS. PART XVII. A DECARBOXYLATIVE SULPHONYLATION OF CARBOXYLIC ACIDS
Barton, Derek H. R.,Lacher, Brigitte,Misterkiewicz, Boguslaw,Zard, Samir Z.
, p. 1153 - 1158 (2007/10/02)
Irradiation with visible light of N-hydroxy-2-thiopyridone esters 1 in the presence of sulphur dioxide gave the corresponding thiosulphonates 4 in good yield.These could be converted to sulphones 5 by treatment with KOH and an alkylating agent.Alternative
