102148-04-9Relevant academic research and scientific papers
Silver-Catalyzed Cross-Coupling of Isocyanides and Active Methylene Compounds by a Radical Process
Liu, Jianquan,Liu, Zhenhua,Liao, Peiqiu,Zhang, Lin,Tu, Tao,Bi, Xihe
supporting information, p. 10618 - 10622 (2015/09/02)
Isocyanides are versatile building blocks, and have been extensively exploited in C-H functionalization reactions. However, transition-metal-catalyzed direct C-H functionalization reactions with isocyanides suffer from over-insertion of isocyanides. Repor
N.M.R. Spectroscopical Investigations on 2-Acetyl-3-aminoacrylates
Michalik, M.
, p. 908 - 916 (2007/10/02)
The 2-acetyl-3-aminoacrylates 3 exist as Z/E-isomers, in which intramolecular H-bonds are formed between NH and acetyl or ester groups.The E-isomers are favoured due to the greater acceptor ability of the acetyl compared with ester group.In arylamino substituted compounds 3 a linear correlation with ?p constants have been found for 1H chemical shifts of CH and NH protons and for 13C chemical shifts of C-2 and C-3, respectively, representing an optimal transmission of substituent effects through the enamino system.The barriers of rotation around the C=C-bond of 3 h ave been determined by d n.m.r. spectroscopy.From coalescence phenomena the free activation enthalpies ΔG(excit.) of rotational process are determined and discussed with respect to substituent effects, a thermal rotational mechanism is postulated.
