102160-19-0

Upstream product

• 53566-95-3 4,4'-diformyltriphenylamine 
• 1194-02-1 4-fluorobenzonitrile 
• 62-53-3 aniline 

Downstream Products

• 507225-31-2 N,N-bis(4-cyanophenyl)-N-(4-iodophenyl)amine 
• 181188-86-3 4,4′-(phenylazanediyl)dibenzoic acid 

Relevant academic research and scientific papers

Charge instability of symmetry broken dipolar states in quadrupolar and octupolar triphenylamine derivatives

The quadrupolar and octupolar cyano triphenylamines shows symmetry broken dipolar charge transfer state, however, its stability can be controlled by the rotation of N-C bond of amino and phenylene moiety. the Partner Organisations 2014.

Self-Assembled, Fluorine-Rich Porous Organic Polymers: A Class of Mechanically Stiff and Hydrophobic Materials

Fluorous organic building blocks were utilized to develop two self-assembled, hydrophobic, fluorinated porous organic polymers (FPOPs), namely, FPOP-100 and FPOP-101. Comprehensive mechanical analyses of these functionalised triazine network polymers marked the introduction of mechanical stiffness among all porous organic network materials; the recorded stiffnesses are analogous to those of their organic–inorganic hybrid polymer congeners, that is, metal–organic frameworks. Furthermore, this study introduces a new paradigm for the simultaneous installation of mechanical stiffness and high surface hydrophobicity into polymeric organic networks, with the potential for transfer among all porous solids. Control experiments with non-fluorinated congeners underlined the key role of fluorine, in particular, bis-trifluoromethyl functionalization in realizing the dual features of mechanical stiffness and superhydrophobicity.

Synthesis, luminescence and electrochromism of aromatic poly(amine-amide)s with pendent triphenylamine moietiest

A new triphenylamine-containing aromatic dicarboxylic acid monomer, N,N-bis(4-carboxyphenyl)-N′,N′-diphenyl-1,4-phenylenediamine (2), was synthesized from the amination reaction between 4-aminotriphenylamine and 4-fluorobenzonitrile and subsequent alkaline hydrolysis of the dinitrile intermediate. A series of novel aromatic poly(amine-amide)s with triphenylamine units in the main chain and as the pendent group were prepared from the newly synthesized dicarboxylic acid and various aromatic diamines. These poly(amine-amide)s were amorphous and readily soluble in many organic solvents. All the polymers could be solution-cast into flexible films with good mechanical properties. They had excellent levels of thermal stability associated with high glass-transition temperatures (226-261°C). These polymers exhibited strong UV-vis absorption bands at 350-365 nm in NMP solution. Their photoluminescence spectra showed maximum bands around 512-543 nm in the green region. The hole-transporting and electrochromic properties are examined by electrochemical and spectroelectrochemical methods. Cyclic voltammograms of the poly(amine-amide) 5a prepared from the dicarboxylic acid monomer 2 with a structurally similar diamine monomer N,N-bis(4-aminophenyl)-N′,N′- diphenyl-1,4-phenylenediamine (4a) exhibited four reversible oxidation redox couples in acetonitrile solution at E1/2 = 0.60, 0.80, 0.97 and 1.13V, respectively. All the poly(amine-amide)s exhibited excellent reversibility of electrochromic characteristics by continuous five cyclic scans between 0.0 to 1.30 V, with a color change from the original pale yellowish neutral form to the green and then to blue oxidized forms. The Royal Society of Chemistry 2005.

A one-pot method for the efficient preparation of aromatic nitriles from aldehydes using ammonia, magnesium sulfate, and manganese dioxide

A one-pot and efficient preparation of aromatic nitriles from the corresponding aldehydes was accomplished by treatment with 2 M ammonia solution in 2-propanol, magnesium sulfate, and manganese dioxide in THF at room temperature. This method was found to be compatible with a variety of functionalities such as hydroxyl, ester, and amide.

Triarylamine-based dinitrile and dicarboxylic acid monomers

Triarylamino-based dinitrile and dicarboxylic acid monomers as represented by the formula: STR1 wherein Z is --CN or --COOH and R is selected from the group consisting of --H, --CH3, --N(CH3)2 and --OH.