1021700-91-3Relevant academic research and scientific papers
Synthetic studies on maitotoxin. 2. Stereoselective synthesis of the WXYZA -ring system
Morita, Masayuki,Haketa, Tasuku,Koshino, Hiroyuki,Nakata, Tadashi
supporting information; experimental part, p. 1679 - 1682 (2009/04/12)
The stereoselective synthesis of the WXYZA -ring system of maitotoxin has been accomplished via a linear synthetic approach, in which key reactions were Sml2-induced cyclization of ss-alkoxyacrylate for the construction of the A -, Y-, and X-rings and 6-endo cyclization of hydroxy vinylepoxide for that of the Z- and W-rings.
