1021876-90-3Relevant academic research and scientific papers
Synthetic studies on maitotoxin. 3. Stereoselective synthesis of the BCDE-ring system
Satoh, Masanori,Koshino, Hiroyuki,Nakata, Tadashi
, p. 1683 - 1685 (2008)
The stereoselective synthesis of the BCDE-ring system of maitotoxin has been accomplished through a two-directional strategy for the construction of polycyclic ether. The key reactions involve Sml2-induced double cyclization of a ss-alkoxyacrylate and a double dihydroxylation for construction of the B- and E-rings.
