102208-53-7Relevant academic research and scientific papers
Tandem RCM-isomerization approach to glycals of desoxyheptoses from a common precursor
Schmidt, Bernd,Biernat, Anne
, p. 105 - 108 (2008/04/12)
Ring closing metathesis and tandem RCM-isomerization have been applied to the synthesis of six- to eight-membered oxacycles, starting from a common precursor. The products of the tandem RCM-isomerization sequence are glycals of 3-deoxyheptoses of varying
The Utility of 2,5-Dideoxy-2,5-imino-D-mannitol as a PFP Enzyme Inhibitor
Chorghade, Mukund S.,Cseke, Csaba T.,Liu, Paul S.
, p. 2251 - 2254 (2007/10/02)
2,5-Dideoxy-2,5-imino-D-mannitol was synthesized from an arabinofuranose derivative.Mercuric acetate cyclization of an ene-carbamate was the key step.The compound proved to be an inhibitor of the pyrophosphate-fructose-6-phosphate-1-phosphotransferase (PFP) enzyme and has potential utility in the biorational design of herbicides.
