102231-96-9Relevant academic research and scientific papers
Odorless benzenethiols in synthesis of thioglycosides and its application for glycosylation reactions
Kajimoto, Tetsuya,Ishioka, Yuichi,Katoh, Takahiro,Node, Manabu
, p. 5736 - 5739 (2007/10/03)
p-Octyloxybenzenethiol (2) was synthesized as a new odorless benzenethiol. Moreover, preparation of thioglycosides using 2 and their application for glycosylation reactions were attempted. As a result, it was found that the thioglycosides were as excellen
Synthesis of 4-alkoxy-2-substituted-benzenethiols and their application to thermotropic liquid crystals
Okamoto, Hiroaki,Wu, Jianwei,Morita, Yuki,Takenaka, Shunsuke
, p. 175 - 179 (2007/10/03)
A new synthetic method of 4-alkoxy-2-X-benzenethiols (X = H, halogens, CH3) has been established. In order to confirm the validity as a component of liquid crystal materials, some derivatives of S-(4-alkoxy-2-X-phenyl) 4-R-thiobenzoates (R = CnH2n+1O, CN, NO2, X = halogens, CH3) were prepared. Most of the thioesters exhibit a nematic phase, while the lateral substituents (X) tend to reduce the mesophase thermal stability as well as the melting point. The effect of lateral substituents on the mesomorphic properties is discussed.
The Effect of Two Terminal Alkoxy Groups on the Mesomorphic Properties of 4,4'-Disubstituted Phenylthiobenzoates
Neubert, Mary E.,Ziemnicka-Merchant, Barbara,Jirousek, Michael R.,Laskos, Stanley J.,Leonhardt, Darrin,Sharma, Ram B.
, p. 209 - 240 (2007/10/02)
A select variety of homologs of the dialkoxyphenylthiobenzoates were prepared.Their mesomorphic properties were determined by hot-stage polarizing microscopy and compared with those for the analogous RO-R' and R-OR' thioesters and esters.Unlike
