916497-81-9Relevant academic research and scientific papers
Glycosylation reaction of thioglycosides by using hypervalent iodine(III) reagent as an excellent promoter
Kajimoto, Tetsuya,Morimoto, Koji,Ogawa, Ryosuke,Dohi, Toshifumi,Kita, Yasuyuki
, p. 838 - 844 (2016/07/13)
Thioglycosides are available donors in glycosylation due to the stability of the anomeric C-S bond under general reaction conditions of protection and deprotection, and offer orthogonality in their activation. We report now that the hypervalent iodine eff
Phenyliodine bis(trifluoroacetate) (PIFA) as an excellent promoter of 2-deoxy-2-phthalimido-1-thioglycosides in the presence of triflic acid in glycosylation reactions
Kajimoto, Tetsuya,Morimoto, Koji,Ogawa, Ryosuke,Dohi, Toshifumi,Kita, Yasuyuki
supporting information, p. 2138 - 2142 (2015/03/31)
A combination of phenyliodine bis(trifluoroacetate) (PIFA) and trifluoromethanesulfonic acid was found to be an effective activator for the glycosylation reaction, of which the glycosyl donor was p-(octyloxy)phenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido
Odorless benzenethiols in synthesis of thioglycosides and its application for glycosylation reactions
Kajimoto, Tetsuya,Ishioka, Yuichi,Katoh, Takahiro,Node, Manabu
, p. 5736 - 5739 (2007/10/03)
p-Octyloxybenzenethiol (2) was synthesized as a new odorless benzenethiol. Moreover, preparation of thioglycosides using 2 and their application for glycosylation reactions were attempted. As a result, it was found that the thioglycosides were as excellen
