102235-50-7

Upstream product

• 1256091-53-8 meso-1,5-hexadiene-3,4-diol 
• 100-39-0 benzyl bromide 

Downstream Products

• 102235-56-3 3,4,5-Tri-O-benzyl-2,6-didesoxy-D-ribo-hexitol 
• 102235-57-4 3,4,5-Tri-O-benzyl-2,6-didesoxy-D-ribo-aldehydo-hexose 
• 102235-55-2 2,3,4-Tri-O-benzyl-1,5,6-tridesoxy-L-ribo-hex-5-enitol 
• 102235-54-1 4-O-Benzyl-1,5,6-tridesoxy-L-ribo-hex-5-enitol 
• 102235-51-8 1,2-Anhydro-4-O-benzyl-5,6-didesoxy-L-ribo-hex-5-enitol 

Relevant academic research and scientific papers

De novo Synthesis of Carbohydrates and Related Natural Products, 29 - Synthesis of Partially Protected Carbohydrates from meso-Divinylglycol

Selective mono-O-benzylation of meso-divinylglycol (1) and subsequent Sharpless epoxidation afford the enantiomerically pure epoxide 3 which was cleaved with different nucleophiles at carbon atom 1.Cleavage with titanium tetrabenzylate affords directly th

De novo Synthesis of Carbohydrates and Related Natural Products, 22. - Synthesis of D-Digitoxose from meso-Divinylglycol

Selective monobenzylation of meso- and rac-divinylglycol (2-m and 2-d,l) affords racemates (+/-)-8 and (+/-)-10, respectively; they are transferred with the help of the Sharpless method under kinetic racemate resolution diastereoselectively into the enant