102255-05-0

Basic information

• Product Name: (1R,4R,5R,6R)-2,7-dioxabicyclo[2.2.1]heptane-5,6-diol (non-preferred name)
• CAS NO: 102255-05-0
• Molecular Formula: C₅H₈O₄
• Molecular Weight: 132.1146
• Mol File: 102255-05-0.mol
• Article Data: 4

Chemical Properties

• Refractive Index: 1.591
• CAS DataBase Reference: (1R,4R,5R,6R)-2,7-dioxabicyclo[2.2.1]heptane-5,6-diol (non-preferred name)(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,4R,5R,6R)-2,7-dioxabicyclo[2.2.1]heptane-5,6-diol (non-preferred name)(102255-05-0)
• EPA Substance Registry System: (1R,4R,5R,6R)-2,7-dioxabicyclo[2.2.1]heptane-5,6-diol (non-preferred name)(102255-05-0)

Safety Data

• Hazardous Substances Data: 102255-05-0(Hazardous Substances Data)

Upstream product

• 59368-14-8 phenyl β-D-ribofuranoside 
• 683-60-3 sodium isopropylate 
• 67-63-0 isopropyl alcohol 
• 76035-75-1 1,5-Anhydro-2,3-O-benzyliden-β-D-ribofuranose 
• 77881-79-9 1,5-Anhydro-exo-2,3-O-benzyliden-β-D-lyxofuranose 
• 87-72-9 D-Xylose 
• 644-76-8 1,6-anhydro-β-D-galactopyranose 
• 77852-54-1 1,6-Anhydro-exo-3,4-O-bezyliden-β-D-lyxo-hexopyranos-2-ulose 
• 71021-25-5 1,6-anhydro-3,4-O-(S)-benzylidene-β-D-galactopyranose 

Downstream Products

• 87411-97-0 1,4-anhydro-2,3-di-O-benzyl-α-D-ribopyranose 

Relevant articles and documents

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1,5-Anhydro-beta-L-arabinofuranose from pyrolysis of plant cell wall materials (biomass).

Three types of agricultural waste material having a significant content of L-arabinose have been subjected to mild, vacuum pyrolysis, and yields of 1,5-anhydro-L-arabinofuranose (1) determined. In corn bran, approximately 40% of the L-arabinose is converted into 1, and this conversion is increased to 78% when the bran is subjected to prior acid washing. The inner and outer barks of ponderosa pine give approximately 30% conversion of their L-arabinose content into 1, but orange peel gives only 9% conversion. A mechanism is postulated involving pyrolytic scission of pendant L-arabinofuranose units from polysaccharides, with cyclization to produce 1.

Photolytische Decarbonylierung von Anhydrozucker-Ulosen zur Synthese von 1,5-Anhydro-β-D-lyxo- und -ribofuranosen sowie 2,6-Anhydro-β-D-psicofuranosen

By photochemical decarbonylation of the 1,6-anhydro-2- (1) and -4-uloses (3) with D-lyxo configuration stereoselective ring contractions yield the 1,5-anhydro-β-D-lyxofuranose derivative 2.Via corresponding transformations the benzylidene derivative 9 is