1022915-92-9Relevant academic research and scientific papers
Palladium-catalyzed direct CH bond arylation of simple arenes with aryltrimethylsilanes
Funaki, Kenji,Kawai, Hiroshi,Sato, Tetsuo,Oi, Shuichi
supporting information; experimental part, p. 1050 - 1052 (2011/12/05)
Direct CH bond arylation of arenes with aryltrimethylsilanes catalyzed by PdCl2 in the presence of CuCl2 as an oxidant has been developed. In addition to the role as the oxidant, CuCl2 is found to be necessary for the selective crosscoupling reaction.
Direct C-H bond arylation of arenes with aryltin reagents catalysed by palladium complexes
Kawai, Hiroshi,Kobayashi, Yasuhiro,Oi, Shuichi,Inoue, Yoshio
, p. 1464 - 1466 (2008/12/21)
Direct C-H bond arylation of simple arenes with aryltin reagents has been successfully catalysed by PdCl2 in the presence of CuCl2. CuCl2 proved to be an activator for a palladium intermediate as well as an oxidant. The Royal Society of Chemistry.
