102303-79-7Relevant academic research and scientific papers
Condensation of 2-Nitrobenzaldehyde with Pyrazolin-5-ones. Structure of 4-(2'-Nitrobenzylidene)pyrazolin-5-ones and their Reductive Cyclization
Danel, A.,Tomasik, P.
, p. 1013 - 1017 (2007/10/02)
The condensation of 1-H-3-methyl-, 3-methyl-1-phenyl-, 1,3-diphenyl- and 1-methyl-3-phenyl-pyrazolin-5-ones with 2-nitrobenzaldehyde resulted in forming the corresponding 4-(2'-nitrobenzylidene)pyrazolin-5-ones.In some cases these products were assisted b
New Aspects in the Reaction of Azomethines with Cyclic CH-Acidic Compounds
Hennig, Lothar,Alva-Astudillo, Mario,Mann, Gerhard,Kappe, Thomas
, p. 571 - 580 (2007/10/02)
Treatment of substituted benzylidene anilines 1a - f with cyclic CH-acidic compounds 2a - m in ethanol at room temperature yields in addition/elimination reactions the corresponding arylidene derivatives 4 and the 2:1 adducts 5.The addition products 3, which are formed as intermediates, could not be isolated in any case.The donor/acceptor effect of the substituents on the benzylidene moiety influences to a significant extent the reactivity towards the azomethine carbon. Keywords.Azomethine; CH-Acidic compound; Addition/elimination reaction.
