102312-78-7Relevant articles and documents
Rhodium-catalyzed allyl transfer from homoallyl alcohols to acrylate esters via retro-allylation
Jang, Minsul,Hayashi, Sayuri,Hirano, Koji,Yorimitsu, Hideki,Oshima, Koichiro
, p. 4003 - 4005 (2007)
Retro-allylation of homoallyl alcohols by rhodium catalysts occurs to generate allylrhodium species. Insertion of acrylate esters to the allylrhodiums proceeds to give the corresponding 2,5-hexadienoate esters in situ. Subsequent isomerization or iterativ
Synthesis of Novel C 2-Symmetric Sulfur-Based Catalysts: Asymmetric Formation of Halo- and Seleno-Functionalized Normal- and Medium-Sized Rings
Jana, Sadhan,Kumar, Sangit,Rathore, Vandana,Verma, Ajay
supporting information, p. 1667 - 1672 (2019/08/28)
The synthesis of novel, highly functionalized, C 2 -symmetric sulfur-based catalysts is developed and their catalytic applications are explored in asymmetric bromo-, iodo- and seleno-functionalizations of alkenoic acids. This protocol provides
Asymmetric bromolactonization catalyzed by a C3-symmetric chiral trisimidazoline
Murai, Kenichi,Matsushita, Tomoyo,Nakamura, Akira,Fukushima, Shunsuke,Shimura, Masato,Fujioka, Hiromichi
supporting information; experimental part, p. 9174 - 9177 (2011/02/26)
A productive alliance: In an enantioselective organocatalytic bromolactonization of 5-substituted hex-5-enoic acids (see scheme), it appears that the formation of an ion pair through interaction of the trisimidazoline catalyst 1 with the substrate both cr
