102334-22-5

Upstream product

• 50-00-0 formaldehyd 
• 1569-69-3 Cyclohexanethiol 
• 75-52-5 nitromethane 

Downstream Products

• 102334-20-3 C₁₈H₂₈N₂S₂ 
• 102334-21-4 Bis(cyclohexylthio)methan-mono-S-(N-tosyl)-imid 
• 102334-16-7 C₁₉H₂₈ClNS₂ 
• 82386-41-2 bis(cyclohexanesulfonyl)methane 
• 102334-19-0 C₁₉H₂₈N₂O₂S₂ 
• 102334-15-6 C₁₉H₂₉NS₂ 
• 102334-17-8 C₂₀H₃₁NS₂ 
• 102334-18-9 C₂₀H₂₈N₂S₂ 
• 82407-38-3 1,1,5,5-Tetrakis(cyclohexylsulfonyl)-3-thiapentane 
• 102333-94-8 2-(Bis-cyclohexylsulfanyl-methyl)-4-chloro-phenylamine 
• 102333-96-0 3-(Bis-cyclohexylsulfanyl-methyl)-pyridin-2-ylamine 
• 102334-25-8 2-(Bis-cyclohexylsulfanyl-methyl)-3-methyl-phenylamine 
• 102333-95-9 2-(Bis-cyclohexylsulfanyl-methyl)-5-methyl-phenylamine 
• 102333-93-7 2-(Bis-cyclohexylsulfanyl-methyl)-phenylamine 

Relevant academic research and scientific papers

Sc(OTf)3-Catalyzed Synthesis of Symmetrical Dithioacetals and Bisarylmethanes Using Nitromethane as a Methylene Source

Use of nitromethane as an electrophilic methylene source for the synthesis of symmetrical dithioacetals and bisarylmethanes has been showcased using Sc(OTf)3 as a catalyst. The procedure allows straightforward access to the densely functionalized dithioacetals and bisarylmethanes under mild conditions. Additionally, the method has been applied for the synthesis of antimalarial tetramethyl mellotojaponin C and anticancer dimeric phloroglucinol derivative.

THIOALKYLATION. VII. CONDENSATION OF 1,3-DISULFONES WITH FORMALDEHYDE AND POTASSIUM HYDROSULFIDE

1,1,5,5-Tetrakis(butylsulfonyl)-, 1,1,5,5,-tetrakis(cyclohexylsulfonyl)-, and 1,1,5,5-tetrakis(phenylsulfonyl)-3-thiapentanes were obtained by the reaction of bis(butylsulfonyl)-, bis(cyclohexylsulfonyl)-, and bis(phenylsulfonyl)methanes respectively with formaldehyde and potassium hydrosulfide in molar ratios of 2:2:1.