102357-46-0

Basic information

• Product Name: (3S,4R)-3-Benzyloxy-7-(2-methyl-[1,3]dioxolan-2-yl)-2-trimethylsilanyl-hept-1-en-4-ol
• CAS NO: 102357-46-0
• Molecular Weight: 378.584
• Mol File: 102357-46-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3S,4R)-3-Benzyloxy-7-(2-methyl-[1,3]dioxolan-2-yl)-2-trimethylsilanyl-hept-1-en-4-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,4R)-3-Benzyloxy-7-(2-methyl-[1,3]dioxolan-2-yl)-2-trimethylsilanyl-hept-1-en-4-ol(102357-46-0)
• EPA Substance Registry System: (3S,4R)-3-Benzyloxy-7-(2-methyl-[1,3]dioxolan-2-yl)-2-trimethylsilanyl-hept-1-en-4-ol(102357-46-0)

Safety Data

• Hazardous Substances Data: 102357-46-0(Hazardous Substances Data)

Upstream product

• 24400-75-7 ethylene-cetal de la bromo-5 pentanone-2 
• 102357-32-4 (S)-2-Benzyloxy-3-trimethylsilanyl-but-3-enal 

Downstream Products

• 102357-49-3 (3S,4S)-3-Benzyloxy-7-(2-methyl-[1,3]dioxolan-2-yl)-2-trimethylsilanyl-hept-1-en-4-ol 
• 102357-47-1 (3R,4R)-3-Benzyloxy-7-(2-methyl-[1,3]dioxolan-2-yl)-hept-1-en-4-ol 

Relevant articles and documents

Stereocontrolled Synthesis of Four Possible Stereoisomers of Vicinal Diol Derivatives via Relative 1,2-Asymmetric Induction. Preparation of Optically Active exo- and endo-Brevicomin

Four possible stereoisomers of vicinal diol derivatives were synthesized stereoselectively by nucleophilic addition to α-alkoxy-β-trimethylsilyl-β,γ-unsaturated carbonyl compounds and this reaction was applied to the synthesis of exo- and endo-brevicomin.