1023641-73-7Relevant academic research and scientific papers
Regioselective synthesis of optically active trifluoromethyl group substituted allylic amines by palladium-catalyzed allylic amination
Hirakawa, Takuya,Ikeda, Kazunori,Ogasa, Hiroshi,Kawatsura, Motoi,Itoh, Toshiyuki
experimental part, p. 2887 - 2890 (2011/03/19)
We succeeded in the regioselective synthesis of chiral trifluoromethyl group substituted allylic amines from chiral allyl acetate using two types of palladium catalysts. Furthermore, we found that the kinetic resolution had occurred during the isomerizati
Regioselective synthesis of trifluoromethyl group substituted allylic amines via palladium-catalyzed allylic amination
Kawatsura, Motoi,Hirakawa, Takuya,Tanaka, Tomoko,Ikeda, Daiji,Hayase, Shuichi,Itoh, Toshiyuki
, p. 2450 - 2453 (2008/09/20)
The palladium-catalyzed regioselective allylic amination of α-trifluoromethylated allyl acetate occurred using Pd(OAc)2/DPPE and [Pd(π-allyl)(cod)]BF4/DPPF. The selective formation of the γ-product was attained by Pd(OAc)2
