1264749-53-2Relevant academic research and scientific papers
Enantioselective allylic amination of trifluoromethyl group substituted racemic and unsymmetrical 1,3-disubstituted allylic esters by palladium catalysts
Kawatsura, Motoi,Terasaki, Shou,Minakawa, Maki,Hirakawa, Takuya,Ikeda, Kazunori,Itoh, Toshiyuki
supporting information, p. 2442 - 2445 (2014/05/20)
The palladium-catalyzed regio- and enantioselective allylic amination of trifluoromethyl group substituted racemic and unsymmetrical 1,3-disubstituted allylic esters has been accomplished. The enantioselective formation of the α-type allylic amines was at
Regioselective synthesis of optically active trifluoromethyl group substituted allylic amines by palladium-catalyzed allylic amination
Hirakawa, Takuya,Ikeda, Kazunori,Ogasa, Hiroshi,Kawatsura, Motoi,Itoh, Toshiyuki
, p. 2887 - 2890 (2011/03/19)
We succeeded in the regioselective synthesis of chiral trifluoromethyl group substituted allylic amines from chiral allyl acetate using two types of palladium catalysts. Furthermore, we found that the kinetic resolution had occurred during the isomerizati
