102367-86-2Relevant academic research and scientific papers
STEREOSELECTIVE TOTAL SYNTHESIS OF (+/-)-ISOCELORBICOL
Huffman, John W.,Raveendranath, Panolil C.
, p. 5557 - 5566 (2007/10/02)
A completely stereoselective total synthesis of the naturally occuring polyhydroxyagarofuran, (+/-)-isocelorbicol (1) is described.The readily available α-agarofuran derivative 3 was converted to 3β-hydroxy-9-keto-β-agarofuran (6) by epoxidation followed
Stereoselective Total Synthesis of (+/-)-Isocelorbicol
Huffman, John W.,Raveendranath, Panolil C.
, p. 2148 - 2150 (2007/10/02)
The naturally occurring trihydroxyagarofuran (+/-)-isocelorbicol (1) has been synthesized in 15 steps (3.2percent) from 9-keto-α-agarofuran (2).This completely stereoselective synthesis includes an osmium tetraoxide oxidation in which the reagent attacks
