1023921-55-2Relevant academic research and scientific papers
2,4,6-Tris(4-iodophenoxy)-1,3,5-triazine as a new recyclable "iodoarene" for in situ generation of hypervalent iodine(III) reagent for α-tosyloxylation of enolizable ketones
Thorat, Prerana B.,Bhong, Bhagyashree Y.,Shelke, Amol V.,Karade, Nandkishor N.
, p. 3332 - 3335 (2014/06/09)
The synthesis of 2,4,6-tris[(4-iodo)phenoxy)]-1,3,5-triazine 6, as a new recyclable nonpolymeric analogue of iodobenzene is achieved using the reaction of 2,4,6-trichloro-1,3,5-triazine with 4-iodophenol in the presence of KOH. The application of 6 as a r
Enantioselective synthesis of 1-arylethanediols by rhodium-catalyzed transfer hydrogenation of α-tosyloxyarylketones
Lee, Do-Min,Kumaraswamy, Gullapalli,Lee, Kee-In
experimental part, p. 73 - 78 (2010/03/26)
Catalytic transfer hydrogenation of α-tosyloxyarylketones mediated by a chiral rhodium complex using an azeotropic mixture of formic acid/triethylamine afforded the corresponding 1-arylethanediol monotosylates in excellent yield with high enantioselectivity.
Iodoxolone-based hypervalent iodine reagents
Shah, Azhar-Ul-Haq A.,Khan, Zulfiqar A.,Choudhary, Naila,Lohoelter, Christine,Schaefer, Sascha,Marie, Guillaume P.L.,Farooq, Umar,Witulski, Bernhard,Wirth, Thomas
supporting information; experimental part, p. 3578 - 3581 (2011/02/22)
Image Persented The fast access to simple (Z)-3-iodo acrylic acid derivatives which can be easily oxidized to the corresponding hypervalent iodine(III) reagents is described. They can be used for various reactions with superior or similar reactivity as conventional hypervalent iodine(III) reagents.
Direct α-oxytosylation of ketones by using pentavalent organobismuth reagents
Sakurai, Naoto,Mukaiyama, Teruaki
, p. 388 - 389 (2008/09/20)
A new method for the preparation of α-tosyloxy ketones by a direct oxytosylation of ketones using a combination of heterocyclic pentavalent organobismuth compounds and p-toluenesulfonic acid monohydrate is described. Copyright
