102423-44-9

Upstream product

• 104-87-0 4-methyl-benzaldehyde 
• 86672-63-1 4-amino-2,4-dihydro-2-methyl-5-(methylthio)-3H-1,2,4-triazole-3-thione 

Downstream Products

• 113385-50-5 C₂₀H₁₉BrN₄OS₂ 
• 113385-45-8 (6S,7R)-7-(4-Bromo-benzoyl)-1-methyl-3-methylsulfanyl-6-p-tolyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazin-1-ium; bromide 
• 102423-54-1 1-methyl-6-(4-methylphenyl)-3-(methylthio)-1,2,4-triazolo<3,4-b><1,3,4>thiadiazolium chloride 
• 113385-49-2 1-methyl-3-methylthio-6-phenyl-7H-1,2,4-triazolo<3,4-b><1,3,4>thiadiazinium chloride 

Relevant academic research and scientific papers

Synthesis of 6,7-dihydro-5H-1,2,4-triazolothiadiazines by a C-C Ring Cyclization under Mild Conditions

The reaction between Schiff bases derived from 4-amino-2-methyl-5-methylthio-2H-1,2,4-triazole-3(4H)-thione and phenacyl bromides yields 7-aroyl-6-aryl-6,7-dihydro-1-methyl-3-methylthio-5H-1,2,4-triazolothiadiazinium bromides .The

Iminophosphorane-mediated Syntheses of Cationic and Mesoionic Derivatives of 1,2,4-Triazolothiadiazole

Two general methods are reported for the preparation of 1,2,4-triazolothiadiazolium salts 4 from 4-amino-2,4-dihydro-2-methyl-5-(methylthio)-3H-1,2,4-triazol-3-thione (1).The first one involves the initial formation of arylidene derivatives