102434-45-7Relevant academic research and scientific papers
Corroboration of Techniques for Assigning Absolute Configuration: Lacinilene C Methyl Ether as an Exemplary Study
Stipanovic, Robert D.,McCormick, John P.,Schlemper, Elmer O.,Hamper, Bruce C.,Shinmyozu, Teruo,Pirkle, William H.
, p. 2500 - 2504 (2007/10/02)
Methods for determination of absolute configuration were independently applied to the phytoalexin lacinilene C methyl ether.The results from circular dichroism, NMR spectroscopy utilizing chiral solvating agents, and chiral stationary phase chromatography allow assignment of the R configuration to (+)-lacinilene C methyl ether.This assignment was verified by X-ray diffraction.Chemical conversion permitted assignment of the R configuration to (+)-lacinilene C.
