1024585-75-8Relevant academic research and scientific papers
An unexpected silver triflate catalyzed reaction of 2-alkynylbenzaldehyde with 2-isocyanoacetate
Zheng, Danqing,Li, Shaoyu,Wu, Jie
supporting information; experimental part, p. 2655 - 2657 (2012/07/16)
An unexpected silver triflate catalyzed reaction of 2-alkynylbenzaldehyde with 2-isocyanoacetate provides an efficient route for the generation of isoquinolines. The reaction proceeds smoothly in air under mild conditions with high efficiency.
A tandem approach to isoquinolines from 2-azido-3-arylacrylates and α-diazocarbonyl compounds
Yang, Yun-Yun,Shou, Wang-Ge,Chen, Zheng-Bo,Hong, Deng,Wang, Yan-Guang
, p. 3928 - 3930 (2008/09/19)
(Chemical Equation Presented) 2-Azido-3-arylacrylates react with α-diazocarbonyl compounds and triphenylphosphine to furnish isoquinolines in 60-92% yields. The tandem process involves a Wolff rearrangement, an aza-Wittig reaction, and an electrocyclic ri
