1024702-46-2Relevant academic research and scientific papers
Stereoselective insertion of rhodium carbenoid to water under control with intramolecular participation of hydroxy group
Sugimura, Takashi,Nagai, Takao
, p. 286 - 287 (2008)
A chiral diazo ester having a hydroxy group in the proper geometry produces an adduct with water up to 92% de upon treatment with a rhodium catalyst. This high stereoselectivity is attributable to the intramolecular hydrogen bond between the internal hydroxy group and the rhodium carbenoid. Copyright
