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IrH2(H2)2(P(C6H11)3)2(1+) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

102493-46-9

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102493-46-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 102493-46-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,2,4,9 and 3 respectively; the second part has 2 digits, 4 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 102493-46:
(8*1)+(7*0)+(6*2)+(5*4)+(4*9)+(3*3)+(2*4)+(1*6)=99
99 % 10 = 9
So 102493-46-9 is a valid CAS Registry Number.

102493-46-9Relevant academic research and scientific papers

Some Molecular Hydrogen Complexes of Iridium

Crabtree, Robert H.,Lavin, Maryellen,Bonneviot, L.

, p. 4032 - 4037 (2007/10/02)

The new molecular hydrogen complexes + (bq = 7,8-benzoquinolinate, L = PPh3 or PCy3) and + are described.A 1H NMR T1 criterion is proposed for detecting such complexes.Deprotonation of the coordinated H2 is described.The mechanism of hydrogenolysis of d0 alkyls is discussed and a dihydrogen complex proposed as intermediate.

(1+) : A Non-classical Polyhydride Complex

Crabtree, Robert H.,Lavin, Maryellen

, p. 1661 - 1662 (2007/10/02)

(Cy = cyclohexyl) is shown by n.m.r. evidence, including T1 measurements, to undergo protonation to give the title complex, a bis(dihydrogen) dihydride, the first example of a non-classical polyhydride complex.

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