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Usage

Uses

Used in Polymer Industry:
[bis[(trifluoromethyl)sulphonyl]methyl]benzene is used as a catalyst for the polymerization of epoxides. Its ability to initiate and control the polymerization process results in the formation of polymers with specific properties, such as high thermal stability and resistance to degradation, making them suitable for various applications, including automotive, aerospace, and electronics industries.
Used in Organometallic Chemistry:
In organometallic chemistry, [bis[(trifluoromethyl)sulphonyl]methyl]benzene is used in the protonation of organometallic species. This process promotes a variety of reactions, such as reductive elimination, trimerization of alkynes, olefin isomerization, and hydroformylation reactions. These reactions are crucial in the synthesis of complex organic molecules and the development of new materials with unique properties.
Used in Pharmaceutical Industry:
[bis[(trifluoromethyl)sulphonyl]methyl]benzene can be employed as a building block or intermediate in the synthesis of pharmaceutical compounds. Its unique structure and reactivity can be harnessed to create new drugs with improved efficacy and selectivity, potentially leading to breakthroughs in the treatment of various diseases and medical conditions.
Used in Chemical Research:
[bis[(trifluoromethyl)sulphonyl]methyl]benzene is also used as a research tool in chemical laboratories. Its properties and reactivity make it an interesting subject for studies aimed at understanding fundamental chemical processes, developing new synthetic methods, and exploring the potential applications of [bis[(trifluoromethyl)sulphonyl]methyl]benzene in various fields.

InChI:InChI=1/C9H6F6O4S2/c10-8(11,12)20(16,17)7(6-4-2-1-3-5-6)21(18,19)9(13,14)15/h1-5,7H

Upstream product

• 335-05-7 Trifluoromethanesulfonyl fluoride 
• 6921-34-2 benzylmagnesium chloride 
• 132273-36-0 phenyliodonium bis(trifluoromethylsulfonyl)methylide 
• 71-43-2 benzene 
• 358-23-6 trifluoromethylsulfonic anhydride 
• 4855-02-1 benzyl trifluoromethyl sulfone 
• 62-53-3 aniline 
• 100-39-0 benzyl bromide 

Downstream Products

• 102493-46-9 IrH₂(H₂)2(P(C₆H₁₁)3)2⁽¹⁺⁾ 
• 98838-00-7 (P(C₆H₅)3)3Rh⁽¹⁺⁾*((C₆H₅)C(SO₂CF₃)2)^(1-)=P₃(C₆H₅)9Rh(C₆H₅)C(SO₂CF₃)2 
• 102493-44-7 C₄₉H₄₁IrNP₂⁽¹⁺⁾ 
• 138647-49-1 4-Trifluoromethanesulfonyloxy-3,6-dihydro-2H-pyridine-1-carboxylic acid tert-butyl ester 
• 880158-60-1 trifluoro-methanesulfonic acid 4-(tert-butoxycarbonylamino-methyl)-2-methoxy-phenyl ester 
• 101141-60-0 [((C₆H₅)3P)4Ru₂H₂(CF₃SO₂)(CO)2]⁽¹⁺⁾*[(C₆H₅)C(SO₂CF₃)2]^(1-) = [((C₆H₅)3P)4Ru₂H₂(CF₃SO₂)(CO)2](C₆H₅)C(SO₂CF₃)2 

Relevant academic research and scientific papers

Facile synthesis of aryl- and alkyl-bis(trifluoromethylsulfonyl)methanes

Various arylbis(trifluoromethylsulfonyl)methanes (1) have been synthesized by reacting the corresponding benzylic halides with sodium trifluoromethanesulfinate and then with triflic anhydride. In addition, when the aryl group of 1 is a pentafluorophenyl group, the nucleophilic para-substitution of the aryl group with alkyllithiums and sodium alkoxides occurs. This reaction is useful for the design of new Bronsted acids.

A new synthetic route to aryl bis(perfluoroalkanesulfonyl)methanes; structures of tolyldiazonium bis(trifluoromethanesulfonyl)methide and 4-nitrophenylhydrazono bis(trifluoromethanesulfonyl)methane

Aryl bis(perfluoroalkanesulfonyl)methanes have been prepared in high yield by the pyrolysis of arenediazonium bis(perfluoroalkanesulfonyl)methides obtained from the reaction of arenediazonium chlorides with potassium bis(perfluoroalkanesulfonyl)methides.Heating p-nitrophenyldiazonium bis(trifluoromethanesulfonyl)methides resulted in a rearrangement to 4-nitrophenylhydrazono bis(trifluoromethanesulfonyl)methane.The X-ray structure analyses of 4-CH3C6H4N2(+)(CF3SO2)2CH(-) and 4-NO2C6H4NHN=C(SO2CF3)2 are presented.

Phenyliodonium Bis(Perfluoroalkanesulphonyl) Methide; Synthesis and Reactions as a Precursor of Bis(Perfluoroalkanesulphonyl) Carbene

Photoreaction of the title compound PhI+-C(RFSO2)2 which was synthesised by the reaction of bis(perfluoroalkanesulphonyl) methane with diacetoxyiodobenzene, with alkene, methanol, bromine and benzene gave corresponding addition or insertion products, via the bis(perfluoroalkanesulphonyl) carbene, (RFSO2)C: intermediate.

Catalyst system containing a fluorinated acid and a polyvalent tin compound

A catalyst system is provided which comprises a fluorinated acid and a polyvalent tin compound. The catalyst system can be used to prepare hydroxyl-terminated poly(haloalkylene ethers).