102503-95-7Relevant academic research and scientific papers
Reductive intramolecular Henry reactions induced by Stryker's reagent
Chung, Wing Ki,Chiu, Pauline
, p. 55 - 58 (2007/10/03)
Conjugate reductions of nitroalkenes by Stryker's reagent are ensued by intramolecular aldol reactions to produce β-nitroalcohols in good yield, constituting the first examples of reductive Henry reactions.
β-CARBONYL RADICALS AS THREE-CARBON BUILDING BLOCKS FOR CARBON-CARBON BOND FORMING REACTIONS
Giese, Bernd,Horler, Hans
, p. 4025 - 4038 (2007/10/02)
From aldehydes, ketones and esters β-carbonyl radicals 47 can be generated via enolization, cyclopropanation, solvomercuration and reduction with NaBH4.Radicals 47 react with electron-poor alkenes 27 to give products of CC-bond forming reactions (Tables 1-3).Carbonyl compounds are therefore precursors of three-carbon building blocks.The products result from reactions with "Umpolung".
