1025362-30-4Relevant articles and documents
LDA-mediated selective addition reaction of vinylidenecyclopropanes with aldehydes, ketones, and enones: Facile synthesis of vinylcyclopropenes allenols, and 1,3-enynes
Lu, Jian-Mei,Shi, Min
supporting information; scheme or table, p. 1943 - 1946 (2009/04/18)
Highly selective addition reaction of vinylidenecyclopropanes 1 was realized by treatment with LDA in THF and quenching with aldehydes, ketones, and enones. A number of vinylcyclopropenes, allenols, and 1.3-enynes were obtained selectively in moderate to good yields depending on the nature of different electrophiles.
