1025446-80-3Relevant academic research and scientific papers
A carbohydrate-based approach for the total synthesis of aculeatin D and 6-epi-aculeatin D
Ramana,Srinivas, Burgula
, p. 3915 - 3918 (2008/09/20)
(Chemical Equation Presented) A concise approach for the total synthesis of aculeatin D and 6-epi-aculeatin D employing differentially protected anti,anti-1,3,5-triol alkyne prepared from α-D-glucoheptonic-γ- lactone derivative is documented. Phenol protecting group manipulation for selective O-debenzylation during the hydrogenation of the diyne intermediate and one-pot phenolic oxidation with concomitant spiroketalization highlight the accomplished total synthesis.
