102599-97-3Relevant academic research and scientific papers
Dual reaction pathways in the magnesium-mediated synthesis of aziridines from benzal halides and imines
Biscoe, Mark R.,Fry, Albert J.
, p. 2759 - 2762 (2001)
Reaction between benzal dihalides, benzaldehyde imines, and magnesium in ether affords aziridines in modest yields. Two mechanistic pathways for aziridine formation are discerned. One path involves nucleophilic attack by an alpha-halo Grignard species on
Samarium diiodide/nickel diiodide an efficient system for homo and heterocoupling reactions of imines
Machrouhi, Fouzia,Namy, Jean-Louis
, p. 1315 - 1318 (2007/10/03)
Samarium diiodide in the presence of a catalytic amount of nickel diiodide mediates a very fast dimerization of imines into vicinal diamines and the mixed coupling of imines and ketones to give β-amino alcohols.
