102629-92-5Relevant academic research and scientific papers
Almond oxynitrilase-catalyzed transformation of aldehydes is strongly influenced by naphthyl and alkoxy substituents
Roda, Gabriella,Riva, Sergio,Danieli, Bruno
, p. 3939 - 3949 (2007/10/03)
Different α- and β-substituted aldehydes have been submitted to the catalytic action of almond oxynitrilase (PaHNL), in order to explore the influence of a stereocenter already present in the substrate on the selectivity of this enzyme. The results indicate that naphthyl and alkoxy substituents in the α- and also in the β-position to the aldehyde group significantly influence the stereochemical outcome of the PaHNL-catalyzed transformation.
Chiral Lactols, VI. A Method for the Determination of the Absolute Configuration of Chiral α-Hydroxysubstituted Nitriles, Alkynes, and Aldehydes
Noe, Christian R.,Knollmueller, Max,Oberhauser, Berndt,Steinbauer, Gerhard,Wagner, Ernst
, p. 729 - 743 (2007/10/02)
A rule is given for the determination of the absolute configuration of chiral α-hydroxysubstituted nitriles, alkynes, and aldehydes of type 2 which is based on enantiomer-selectivity in acetal formation of such compounds with a lactol of type 1 and charac
