1026454-37-4

Basic information

• Product Name: C₁₄H₁₇NO₃
• CAS NO: 1026454-37-4
• Molecular Weight: 247.294
• Mol File: 1026454-37-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₁₄H₁₇NO₃(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₁₇NO₃(1026454-37-4)
• EPA Substance Registry System: C₁₄H₁₇NO₃(1026454-37-4)

Safety Data

• Hazardous Substances Data: 1026454-37-4(Hazardous Substances Data)

Upstream product

• 38838-06-1 methyl 5-deoxy-5-iodo-2,3-isopropylidene-β-D-ribofuranoside 
• 100-65-2 N-Phenylhydroxylamine 
• 155934-55-7 (4R,5R)-2,2-dimethyl-5-vinyl-[1,3]dioxolane-4-carbaldehyde 

Downstream Products

• 155855-55-3 (3aR,4S,6R,6aS)-6-anililino-2,2-dimethyl-tetrahydro-3aH-cyclopenta[d][1,3]dioxol-4-ol 
• 155855-52-0 (1R,2S,6S,7S)-4,4-dimethyl-9-phenyl-3,5,8-trioxa-9-aza-tricyclo[5.2.1.0^2,6]decane 

Relevant articles and documents

An improved approach to chiral cyclopentenone building blocks. Total synthesis of pentenomycin I and neplanocin A

An improved approach to enantiomerically pure hydroxylated cyclopentenones is reported here, which involves intramolecular nitrone cycloaddition of sugar-derived chiral pent-4-enals and hex-5-en-ones-2 followed by N-O bond cleavage, quaternization of the amine thus produced, and finally oxidative elimination of the amino group. Synthesis of pentenomycin I and neplanocin A is described following this methodology.