102650-45-3

Upstream product

• 102650-44-2 Benzoic acid (2S,3R,4S,6S)-2-benzyloxymethyl-4-(tert-butyl-dimethyl-silanyloxy)-6-furan-2-yl-6-methoxy-tetrahydro-pyran-3-yl ester 

Downstream Products

• 102650-46-4 Benzoic acid (2R,3R,4S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-2-formyl-6-furan-2-yl-6-methoxy-tetrahydro-pyran-3-yl ester 
• 102650-48-6 Benzoic acid (2R,3S,4R,6R)-4-(tert-butyl-dimethyl-silanyloxy)-6-furan-2-yl-6-methoxy-2-((1S,2S)-1,2,3-trihydroxy-propyl)-tetrahydro-pyran-3-yl ester 
• 102682-12-2 Benzoic acid (2S,3R,4S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-6-furan-2-yl-6-methoxy-2-((Z)-2-methoxycarbonyl-vinyl)-tetrahydro-pyran-3-yl ester 
• 102650-47-5 Benzoic acid (2S,3R,4S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-2-((1R,2S)-1,2-dihydroxy-2-methoxycarbonyl-ethyl)-6-furan-2-yl-6-methoxy-tetrahydro-pyran-3-yl ester 
• 102650-51-1 (2S,4S,5S,6R)-5-Benzoyloxy-4-hydroxy-2-methoxy-6-((1R,2R)-1,2,3-tris-benzoyloxy-propyl)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 102650-52-2 (2S,4S,5S,6R)-4-Benzoyloxy-5-hydroxy-2-methoxy-6-((1R,2R)-1,2,3-tris-benzoyloxy-propyl)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 102650-50-0 (2R,4R,5S,6R)-5-Benzoyloxy-4-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-6-((1S,2S)-1,2,3-tris-benzoyloxy-propyl)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 102650-49-7 C₄₇H₅₀O₁₂Si 

Relevant academic research and scientific papers

The Total Synthesis of (+/-)-N-Acetylneuraminic Acid (NANA): A Remarkable Hydroxylation of a (Z)-Enoate

A total synthesis of the title compound was achieved.A key feature of the synthesis involved a stereospecific hydroxylation of a (Z)-carbomethoxyvinyl pyranoside.