10266-76-9Relevant academic research and scientific papers
Concomitant bromination and lactolisation of unsaturated diols with sodium bromite in aqueous acetic acid
Evans, Gary B.,Grant, Peter K.
, p. 4709 - 4712 (2007/10/03)
The attempted lactonisation of unsaturated diols 8, 13, and 15 using sodium bromite in aqueous acetic acid gave the bromo lactols 9, 16, and 18 respectively. The bromo lactols were converted to their corresponding lactones 10, 17, and 19 using Jones reagent.
Ozonolysis of Derivatives of Labda-8(17),14-dien-13-ol (Manool) and Their Conversion into Large Ring Unsaturated Lactones
Grant, Peter K.,Lai, Chee Kong,Prasad, J. Siva,Yap, Tho Man
, p. 711 - 725 (2007/10/02)
Dehydration of the unstable hydroperoxy ethers (4) and (6) formed on ozonolysis of the manool derivatives (2) and (5) resulted in the formation of the ten-membered unsaturated lactones (11) and (12) in good yield.The results of an investigation into the nature of the hydroxyl group and its spatial relationship to the exocyclic double bond in lactone formation are reported for other manool derivatives.
