1026632-86-9Relevant articles and documents
Radical Alkynyltrifluoromethylation of Alkenes Initiated by an Electron Donor-Acceptor Complex
Jiang, Heng,He, Yanyan,Cheng, Yuanzheng,Yu, Shouyun
, p. 1240 - 1243 (2017)
Radical alkynyltrifluoromethylation of alkenes with actylenic triflones has been achieved. This radical chain reaction is initiated by a catalytic amount of an electron-donor-acceptor complex composed of Togni’s reagent and N-methylmorpholine. This transf
Copper-Catalyzed Trifluoromethylalkynylation of Isocyanides
Lei, Jian,Wu, Xiaoxing,Zhu, Qiang
supporting information, p. 2322 - 2325 (2015/06/02)
The title reaction proceeds with acetylenic triflones and isocyanides under mild conditions using copper as a catalyst. This transformation provides an efficient access to (E)-N-alkyl trifluoromethyl alkynyl ketoimines, which are useful building blocks for the synthesis of CF3-containing N-heterocycles, propargylamines, etc.