102675-78-5Relevant academic research and scientific papers
The Stereoselective Synthesis of Acyclic and Exocyclic Trisubstituted Olefins via a Hydroxyl-Directed Wittig Reaction
Garner, Philip,Ramakanth, Sarabu
, p. 2629 - 2631 (1987)
Both acyclic and cyclic α-hydroxy ketones undergo an accelerated Wittig reaction with stabilized phosphonium ylides to give E-trisubstituted olefins in moderate to good chemical yield.
A NOVEL REARRANGEMENT LEADING TO METHOXYCARBONYLMETHYLATED SILYL ENOL ETHERS
Reissig, Hans-Ulrich
, p. 3943 - 3946 (2007/10/02)
Methyl 2-siloxycyclopropanecarboxylates rearrange smoothly and quantitatively to the corresponding silyl enol ethers (3) by addition of a catalytical amount of iodo trimethylsilane.Scope and limitation of this novel process as well as the synthesis of the electron rich diene (10a) are described.
