10268-61-8

Basic information

• Product Name: Benzoic acid, 2-hydroxy-, 4-methoxyphenyl ester
• CAS NO: 10268-61-8
• Molecular Formula: C14H12O4
• Molecular Weight: 244.247
• Mol File: 10268-61-8.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 2-hydroxy-, 4-methoxyphenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 2-hydroxy-, 4-methoxyphenyl ester(10268-61-8)
• EPA Substance Registry System: Benzoic acid, 2-hydroxy-, 4-methoxyphenyl ester(10268-61-8)

Safety Data

• Hazardous Substances Data: 10268-61-8(Hazardous Substances Data)

Upstream product

• 444-30-4 2-(trifluoromethyl)phenol 
• 150-76-5 4-methoxy-phenol 
• 171771-88-3 2-(4-methoxy-phenoxy)benzonitrile 
• 69-72-7 salicylic acid 
• 5538-51-2 O-acetylsalicyloyl chloride 
• 1916-04-7 2-(4-methoxyphenoxy)benzoic acid 
• 83570-56-3 p-methoxyphenyl-o-acetoxybenzoate 

Downstream Products

• 128916-09-6 2-Allyloxy-benzoic acid 4-methoxy-phenyl ester 
• 6005-12-5 2,3-diphenyl-4H-chromen-4-one 
• 89-71-4 2-Methyl-benzoic acid methyl ester 
• 83570-57-4 2,2'-dihydroxy-5-methoxy benzophenone 
• 150-76-5 4-methoxy-phenol 
• 88599-71-7 2-Carbamoyloxy-benzoic acid 4-methoxy-phenyl ester 

Relevant articles and documents

Synthesis of salicylates from anionically activated aromatic trifluoromethyl group

An efficient approach to salicylates via a novel transformation of anionically activated aromatic trifluoromethyl group is described. Anionically activated trifluoromethyl group can react with phenols/alcohols under alkaline conditions to afford aryl/alkyl salicylates in high yields. Mechanism studies indicate that the carbonyl oxygen atom of ester is from the H2O in the solvent.

Cerium photocatalyzed radical smiles rearrangement of 2-aryloxybenzoic acids

We report herein a cerium photocatalyzed aryl migration from an aryl ether to a carboxylic acid group through radical-Smiles rearrangement. This operationally simple protocol utilizes inexpensive CeCl3as a photocatalyst and converted a variety of 2-aryloxybenzoic acids into aryl-2-hydroxybenzoates in good yields.

A photoredox-neutral Smiles rearrangement of 2-aryloxybenzoic acids

We report on the use of visible light photoredox catalysis for the radical Smiles rearrangement of 2-aryloxybenzoic acids to obtain aryl salicylates. The method is free of noble metals and operationally simple and the reaction can be run under mild batch or flow conditions. Being a redox neutral process, no stoichiometric oxidants or reductants are needed.