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10268-71-0

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10268-71-0 Usage

Description

2-Methoxy-benzoic acid phenyl ester, also known as methyl 2-methoxybenzoate, is a colorless liquid chemical compound with the formula C9H10O3. It is characterized by a fruity odor and is commonly used in the manufacturing of flavors and fragrances due to its pleasant scent. 2-METHOXY-BENZOIC ACID PHENYL ESTER is also utilized in the synthesis of pharmaceuticals and serves as an intermediate in organic chemistry. With its low toxicity and general safety for use in various applications, it is considered a versatile chemical in the industry.

Uses

Used in Flavor and Fragrance Industry:
2-Methoxy-benzoic acid phenyl ester is used as a flavoring agent for its fruity odor, enhancing the taste and aroma of various food products. It is also employed as a fragrance ingredient in perfumes and cosmetics, adding a pleasant scent to these products.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, 2-Methoxy-benzoic acid phenyl ester is used as a key intermediate in the synthesis of various drugs, contributing to the development of new medications and improving existing ones.
Used in Organic Chemistry:
As an intermediate in organic chemistry, 2-Methoxy-benzoic acid phenyl ester is utilized in various chemical reactions and processes, aiding in the production of a wide range of chemical compounds and materials.

Check Digit Verification of cas no

The CAS Registry Mumber 10268-71-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,2,6 and 8 respectively; the second part has 2 digits, 7 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 10268-71:
(7*1)+(6*0)+(5*2)+(4*6)+(3*8)+(2*7)+(1*1)=80
80 % 10 = 0
So 10268-71-0 is a valid CAS Registry Number.
InChI:InChI=1/C14H12O3/c1-16-13-10-6-5-9-12(13)14(15)17-11-7-3-2-4-8-11/h2-10H,1H3

10268-71-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name Phenyl 2-methoxybenzoate

1.2 Other means of identification

Product number -
Other names Benzoic acid,2-methoxy-,phenyl ester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:10268-71-0 SDS

10268-71-0Relevant articles and documents

Palladacycle-catalyzed carbonylation of aryl iodides or bromides with aryl formates

Chen, Guangwei,Leng, Yuting,Yang, Fan,Wang, Shiwei,Wu, Yangjie

, p. 1488 - 1494 (2013)

An efficient palladacycle-catalyzed aromatic carbonylation reaction of aryl formates with aryl iodides or bromides has been developed. Commercially available and easily prepared aryl formates were employed as carbonyl sources without the use of external carbon monoxide. The present catalytic system shows broad functional group tolerance and affords aryl benzoate derivatives in good to excellent yields. Copyright

Transition-Metal-Free DMAP-Mediated Aromatic Esterification of Amides with Organoboronic Acids

Guo, Jiarui,Liu, Lantao,Wang, Tao,Wang, Yanqing,Xu, Kai,Zhang, Yuheng

supporting information, p. 3274 - 3277 (2021/06/26)

A new, transition-metal-free, effective method for aromatic esterification of amides with organoboronic acids has been developed. A wide range of benzoate derivatives were obtained with yields ranging from moderate to good. The catalytic reaction shows a broad substrate scope and excellent functional group tolerance. Conceptually, DMAP mediates the reaction and is crucial for this transformation.

Palladium-Catalyzed Aerobic Oxidative Coupling of Amides with Arylboronic Acids by Cooperative Catalysis

Li, Yue,Wu, Hongxiang,Zeng, Zhuo

supporting information, p. 4357 - 4361 (2019/07/09)

The first fluoride and palladium co-catalyzed conversion of amide to ester through an aerobic oxidative coupling pathway is reported. This new approach presents a practical process that employs easily available oxygen and commercially available arylboronic acids as coupling partners, uses a wide range of N- tosylamides, and proceeds under mild reaction conditions. This protocol demonstrates broad functional group tolerance, and provides an alternative option to synthesize esters from N-tosylamides which obtained by simply N-functionalization of secondary amides.

Mechanistic Insight into Weak Base-Catalyzed Generation of Carbon Monoxide from Phenyl Formate and Its Application to Catalytic Carbonylation at Room Temperature without Use of External Carbon Monoxide Gas

Konishi, Hideyuki,Matsubara, Mika,Mori, Keisuke,Tokiwa, Takaki,Arulmozhiraja, Sundaram,Yamamoto, Yuta,Ishikawa, Yoshinobu,Hashimoto, Hiroshi,Shigeta, Yasuteru,Tokiwa, Hiroaki,Manabe, Kei

supporting information, p. 3592 - 3601 (2017/10/24)

The mechanisms of the weak base-catalyzed generation of carbon monoxide (CO) and phenol from phenyl formate were investigated by experimental and theoretical methods. Kinetic studies revealed a first-order reaction in both phenyl formate and the base. The reaction was found to proceed by an E2 α-elimination pathway, which involves the abstraction of the formyl proton of phenyl formate, simultaneously generating CO and phenoxide. The reaction rate was affected by the substituents on phenyl formate, the polarity of solvents, and the basicity of bases. The mechanistic insight obtained from these studies permitted the chemical control of the rate of CO generation, which was the key to the development of the external CO-free Pd-catalyzed phenoxycarbonylation of haloarenes at room temperature. Because of the mild reaction conditions and wide substrate scope, this phenoxycarbonylation constitutes a general, safe, and practical method to synthesize arenecarboxylic acid esters. (Figure presented.).

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