1026861-04-0

Basic information

• Product Name: C₂₂H₃₄O₆
• CAS NO: 1026861-04-0
• Molecular Weight: 394.508
• Mol File: 1026861-04-0.mol

Chemical Properties

• CAS DataBase Reference: C₂₂H₃₄O₆(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₂H₃₄O₆(1026861-04-0)
• EPA Substance Registry System: C₂₂H₃₄O₆(1026861-04-0)

Safety Data

• Hazardous Substances Data: 1026861-04-0(Hazardous Substances Data)

Upstream product

• 42274-61-3 (2S)-2-(tetrahydro-2H-pyran-2-yloxy)propyl 4-methylbenzenesulfonate 
• 120-80-9 benzene-1,2-diol 

Downstream Products

• 85337-90-2 (1S,8S)-(+)-1,8-dimethyl-4,5-benzo-3,6-dioxaoctane-1,8-diol 

Relevant articles and documents

Recognition by A New Chiral Dimethyl-substituted Phenanthrolino-18-Crown-6 Diester Ligand of the Enantiomers of Various Organic Ammonium Perchlorates

The new chiral dimethyl-substituted phenanthrolino-18-crown-6 diester ligands and (see Figure 1) were prepared through the reactions of 1,10-phenanthroline-2,9-dicarboxylyl dichloride with (S,S)-dimethyl-substituted triethylene glycol and (S,S)-dimethyl-substituted benzotriethylene glycol, respectively.The complexation of (S,S)-3 with the enantiomers of various organic ammonium perchlorates in various solvent systems was studied by 1H nmr spectral techniques and molecular mechanics.The degree of enantiomeric recognition was determined by the difference in the free energy of activation values (ΔΔGC) and the difference in log K values for these interactions.The extensive ? system in the ligand plays an important role for the strong interaction and recognition.The 1H nmr NOESY spectra and molecular mechanics calculations for the interactions of the new ligand with the organic ammonium salts further proved the existence of a ?-? interaction.