10271-46-2

Upstream product

• 58616-86-7 exo-endo-tricyclo[5.2.1.0^2,6]dec-4-ene-3-ol 
• 2825-86-7 3a,4,5,6,7,7a-hexahydro-4,7-methano-1H-indene 
• 17364-68-0 endo-tricyclo<5.2.1.0².⁶>decan-3-one 
• 86594-77-6 Tricyclo[5.2.1.0^2,6]decan-2-ol 
• 3129-29-1 exo-tricyclo[5.2.1.0^2.6]dec-3-ene 
• 17364-68-0 exo-tricyclo<5.2.1.0^2,6>decan-3-one 
• 24529-79-1 (1RS,3aRS,4RS,7SR,7aSR)-3a,4,7,7a-tetrahydro-4,7-methano-1H-inden-1-ol 
• 87238-74-2 exo-2,6-epoxytricyclo<5.2.1.0^2,6>decane 
• 87238-75-3 tricyclo<5.2.1.0².⁶>dec-2(6)-ene 

Relevant academic research and scientific papers

Synthesis and Reactions of Tricyclo2,6>dec-2(6)-ene

The synthesis and some addition reactions of the novel strained olefin, tricyclo2,6>dec-2(6)-ene (5), are described.The stability and reactivity of 5 are discussed with regard to molecular mechanics calculations (MM2).

Structural Effects in Solvolytic Reactions. 51. Examination of the Differences in the Behavior of Secondary and Tertiary U-Shaped Bicyclic Derivatives toward Solvolysis

The solvolyses (acetolysis) of secondary bicyclic tosylates such as cis-bicyclooct-2-yl and 5,6-endo-trimethylene-8-norbornyl and -9-norbornyl proceed with low exo/endo rate ratios (10), unlike secondary 2-norbornyl (280) and the analogous tertiary derivatives wherein the exo/endo rate ratios increase progressively with increasing U-shaped character.The possible factors responsible for this difference in behavior are discussed.One possible factor can be nucleophilic solvent participation in the secondary systems, absent both in secondary 2-norbornyl and in tertiary solvolyses.An examination of the products of acetolysis of a number of bicyclic secondary tosylates reveals predominant inversion during acetolysis, suggesting solvent participation.