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17364-68-0

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17364-68-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 17364-68-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,7,3,6 and 4 respectively; the second part has 2 digits, 6 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 17364-68:
(7*1)+(6*7)+(5*3)+(4*6)+(3*4)+(2*6)+(1*8)=120
120 % 10 = 0
So 17364-68-0 is a valid CAS Registry Number.

17364-68-0Relevant articles and documents

Derivatisation of Saturated Hydrocarbons. The Mechanism of RuO4 Oxidations

Bakke, Jan M.,Braenden, Jon Erik

, p. 418 - 423 (2007/10/02)

The reaction mechanism of RuO4 oxidations of saturated hydrocarbons has been investigated by several methods. (1) By oxidation of endo-tetrahydrodicyclopentadiene (1H) and 2,6-dideuterio-endo-tetrahydrodicyclopentadiene (1D) a kinetic deuterium isotope effect of 5.3 was observed, indicating transfer of a hydrogen species and not a single electron in the rate-determining step. (2) No chlorinated products were formed from the reaction in CCl4.Radical intermediates are therefore not likely. (3) In the presence of chloride ion, 2-chloro-endo-tetrahydrodicyclopentadiene (2-Cl) was formed in addition to endo-tetrahydrodicyclopentadien-2-ol (2-OH), indicating a carbocation intermediate. (4) Further oxidation of 2-OH to bicyclodecane-2,6-dione (8) proceeds via a ruthenium complex with the hydroxy group as the corresponding acetate 2-OAc was not oxidised.These points indicate that the reaction proceeds by hydride abstraction and carbocation formation and not by a cyclic one-step formation of the ruthenium ester from the saturated hydrocarbon.

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