102775-07-5Relevant academic research and scientific papers
CONFORMATIONAL EFFECTS IN ORGANOALUMINUM-PROMOTED PINACOL-TYPE REARRANGEMENT
Suzuki, Keisuke,Tomooka, Katsuhiko,Shimazaki, Masato,Tsuchihashi, Gen-ichi
, p. 4781 - 4784 (1985)
Conformational effects on the reaction course were examined in organoaluminum-promoted pinacol-type rearrangement, using stereo-defined unsymetrical β-mesyloxy alcohols as the probe, where combinational use of DIBAL-Et2AlCl achieved highly selective migration.
