
Tetrahedron Letters p. 4781 - 4784 (1985)
Update date:2022-08-03
Topics:
Suzuki, Keisuke
Tomooka, Katsuhiko
Shimazaki, Masato
Tsuchihashi, Gen-ichi
Conformational effects on the reaction course were examined in organoaluminum-promoted pinacol-type rearrangement, using stereo-defined unsymetrical β-mesyloxy alcohols as the probe, where combinational use of DIBAL-Et2AlCl achieved highly selective migration.
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