1027759-45-0

Basic information

• Product Name: 3,6-anhydro-5-deoxy-1,2-O-isopropylidene-4-(mesyloxymethyl)-β-L-idofuranose
• CAS NO: 1027759-45-0
• Molecular Weight: 294.326
• Mol File: 1027759-45-0.mol

Chemical Properties

• CAS DataBase Reference: 3,6-anhydro-5-deoxy-1,2-O-isopropylidene-4-(mesyloxymethyl)-β-L-idofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 3,6-anhydro-5-deoxy-1,2-O-isopropylidene-4-(mesyloxymethyl)-β-L-idofuranose(1027759-45-0)
• EPA Substance Registry System: 3,6-anhydro-5-deoxy-1,2-O-isopropylidene-4-(mesyloxymethyl)-β-L-idofuranose(1027759-45-0)

Safety Data

• Hazardous Substances Data: 1027759-45-0(Hazardous Substances Data)

Upstream product

• 1027759-08-5 3-O-benzyl-4-(2-hydroxyethyl)-1,2-O-isopropylidene-β-L-arabinofuranose 
• 124-63-0 methanesulfonyl chloride 

Relevant articles and documents

Introduction of vinyl and hydroxymethyl functionalities at C-4 of glucose-derived substrates: Synthesis of spirocyclic, bicyclic, and tricyclic nucleosides

(Chemical Equation Presented) Installing hydroxymethyl and hydroxyethyl substitutions at C-4 through vinylation and hydroboration-oxidation reactions of the C-4 bis-hydroxymethyl derivative of D-glucose based substrate, and inserting heteroatoms thereafter permitted formation of N-, O-, or S-heterocycles leading to [4,5]-or [5,5]-spirocycles and a bicyclo[3.3.0]octane product. Some of the spirocycles were converted to spironucleosides under Vorbrueggen glycosidation reaction conditions. Similarly, the bicyclic product was elaborated to the corresponding bicyclic nucleoside as well as an unexpected tricyclic nucleoside.