1027892-20-1Relevant academic research and scientific papers
Enantioselective preparation of a novel chiral 1,2-diamine
Demay, Stéphane,Kotschy, Andras,Knochel, Paul
, p. 863 - 866 (2001)
A short enantioselective preparation of (1S,2S)-trans-1,2-diamino-3-cyclohexene using a double [3,3]-sigmatropic rearrangement of an allylic bis(imidate) is described (Overman rearrangement). The starting chiral diol is conveniently obtained by enzymatic resolution.
