1028182-40-2

Upstream product

• 13039-93-5 2,2:4,5-di-O-isopropylidene-D-arabinose 
• 100-58-3 phenylmagnesium bromide 
• 108-86-1 bromobenzene 

Downstream Products

• 1028182-43-5 (1R)-O²,O³;O⁴,O⁵-diisopropylidene-O¹-methyl-1-phenyl-D-arabitol 
• 30469-85-3 (1R)-1-phenyl-D-arabitol 
• 1192066-59-3 (4R,4'R,5R)-5-((R)-hexyloxy(phenyl)methyl)-2,2,2',2'-tetramethyl-4,4'-bi(1,3-dioxolane) 
• 1192066-73-1 (4R,4'R,5R)-5-((R)-dodecyloxy(phenyl)methyl)-2,2,2',2'-tetramethyl-4,4'-bi(1,3-dioxolane) 
• 20715-27-9 phenyl((4R,4'R,5S)-2,2,2',2'-tetramethyl-4,4'-bi(1,3-dioxolan)-5-yl)-methanone 

Relevant academic research and scientific papers

Total synthesis of 8-methoxygoniodiol related compounds via chiron approach

The stereoselective synthesis of 8-methoxygoniodiol related compounds was accomplished by using readily available δ-gluconolactone as a chiral source. The stereoselective addition of an aryl Grignard reagent on an aldehyde, stereoselective reduction of a keto group and regioselective opening of a chiral epoxide by ethyl propiolate are the key steps involved in this synthesis.

Total synthesis of 8-methoxygoniodiol via chiron approach

A stereoselective synthesis of 8-methoxygoniodiol is accomplished using readily available δ-gluconolactone as a chiral source. The stereoselective addition of aryl Grignard reagent on aldehyde and regioselective opening of chiral epoxide by ethyl propiola