102845-60-3Relevant academic research and scientific papers
Metallic Base-Induced Cycloadditions of N-(1-Cyanoalkyl)imines via N-Metalated Azomethine Ylides: Enhanced Reactivity and High Regio- and Stereoselectivity
Tsuge, Otohiko,Kanemasa, Shuji,Yorozu, Kiyotaka,Ueno, Kazunori
, p. 3359 - 3366 (2007/10/02)
Lithiation of N-(1-cyanoalkyl)imines with LDA generates new N-lithiated azomethine ylide 1,3-dipoles which show enhanced reactivity toward dipolarophiles.They undergo exclusively regio- and stereoselective 3+2 cycloaddition reaction with α,β-unsaturated e
Stereoselectivity of Cycloaddition of N-(Cyanomethyl)- and N-(α-Cyanobenzyl)imines with Olefinic Dipolarophiles. Synthetic Equivalents of Nitrile Ylide 1,3-Dipoles
Tsuge, Otohiko,Ueno, Kazunori,Kanemasa, Shuji,Yorozu, Kiyotaka
, p. 1809 - 1824 (2007/10/02)
N-(Cyanomethyl)- and N-(α-cyanobenzyl)imines derived from a variety of aldehydes and ketones can tautomerize into N-protonated azomethine ylides which undergo cycloadditions with olefinic dipolarophiles.These cycloadditions are often accompanied by the el
CYCLOADDITIONS OF N-BENZYLIDENEAMINOACETONITRILE AS A SYNTHETIC EQUIVALENT OF METHANENITRILE BENZZLIDE
Tsuge, Otohiko,Kanemasa, Shuji,Yorozu, Kiyotaka,,Ueno, Kazunori
, p. 1601 - 1604 (2007/10/02)
N-Benzylideneaminoacetonitrile is a synthetic equivalent of methanenitrile benzylide via a cycloaddition and elimination sequence.Its reactions with olefinic dipolarophiles provide stereochemically defined 1- or 2-pyrrolines.
